Do you mean they did that actively (using lead as an added sweetener)or was it passively (by proxy though the vessels they used)?
I'm sure it started accidentally but was continued because it magically turned shitty sour wine into sweet wine.
A side note; we still actively use artificial sweeteners from petrochemical sources.
Lead(II) acetate (Pb(CH3COO)2), also known as lead acetate, lead diacetate, plumbous acetate, sugar of lead, lead sugar, salt of Saturn, or Goulard's powder, is a white crystalline chemical compound with a sweet taste.
So clearly (?) it would add a sweet taste, regardless of how much of the acid was chemically consumed.