According to Baye's Theorem, the P(PhD|jobless) = P(jobless|PhD)*P(PhD)/P(jobless)
Where according to [1], P(PhD) = 0.01 (for all PhDs) so assuming roughly half are science, P(PhD) = 0.005, and we get
P(PhD|jobless) = 0.0013, or 0.13%, which means that roughly 1 out of every 1000 jobless people has a PhD.
[1]http://factfinder.census.gov/servlet/QTTable?_bm=y&-geo_...