Odds are, with the amount of RAM available, you get the performance of an in-memory database with Postgres too.
As for a redis-like disk-first database, it would be amazing, but I don't know if it is really possible (unless performance was severely sacrificed). This could be an interesting area to explore.
Redis still has an edge on use cases with auto-expiration.
Besides having all the data structures, I love just connecting to Redis without specifying a database name (there's just a database number, which defaults to 0), a database user, or needing to create a table or a schema. Redis is, so to speak, just there. Not saying this is better than Postgres objectively - I just like it more.