I think it might be better to compare in terms of "passenger mile per unit of greenhouse effect" but then how do you even get to agreement on how to measure the greenhouse effect...
In terms of CO2 true synfuels would be clean in so far as the CO2 would have been captured earlier. The only feasible way to do this would be biomass and the synfuel would either be derived directly from a plant-based source or reuse CO2 captured from terrestrial biomass burning methanize H2 from an electrolysis plant (that would typically be run as an opportunistic sink for intermittent renewable electricity).
That's not to say that proper incentives for car pooling are bad, but it's also no reason to exclude looking at improving the efficiency of planes- especially since fuel costs are so large a portion of their operating costs.
Supposedly a single long over ocean flight costs something the same as a whole year of driving in terms of carbon emission.
Distance isn't everything, many many flights are avoidable/suitable for alternative modes of transport. This [0] estimates that 18% of flights of adults in the UK are "long haul". 40% were either domestic or short haul in Europe, both of which are replacable by trains. The longest domestic flight in the UK is from Gatwick to Inverness, and takes just under 2 hours, or an 8 hour train journey.
[0] https://fullfact.org/economy/do-15-people-take-70-flights/ - (Note this was just the first source I found)
Of course an ICE car doesn't get the same milage as that aircraft, but it's just a factor of 2-3 off. And then there's the difference in emissions and between a jet engine with its jet fuel vs the ICE car. For someone like me, even if I was driving to work, that single vacation would be a significant contribution to my travel CO2 footprint.
[1]: https://www.airmilescalculator.com/distance/osl-to-jfk/
How do you get that? A normal modern car does 5.5 L/100km (~40 mpg) nowadays.
That still isn't 4x though. You can find SUVs that get 4x worse, but they are generally heavy duty trucks doing things that cars cannot do. Per useful mass moved they do better than anything else.