Wolfram's narcissism is so extreme it's just comical. When I was really into complexity science and stuff everyone in the field would joke about it, suggesting a drinking game where you take a shot every time Wolfram refers to how he was a gifted child or started studying math in his teens or single-handedly accomplished some amazing feat. The guy toots his own horn like a circus clown.
It's too bad because he actually does have some very interesting ideas and a good skill at explaining things. His narcissism is self-defeating. He needs to just chill out, write like a normal human being, and publish. Maybe he should take up amateur astronomy. Nothing gives perspective more than carefully observing photons older than the human species with your own eyes.
I sometimes recommend A New Kind of Science with a huge caveat. It's a decent compendium of fascinating cellular automata, complexity, and theoretical CS research with some interesting speculation attached, but (1) Wolfram did not invent all this or do all this work himself, and (2) he takes his speculation too far to the point of flirting with crackpottery. If you can read NKS with those caveats in mind, it's worth at least skimming and taking in the interesting bits.