Facebook probably just hires super bright developers, not PHP developers per se. Those developers can pick up Hack in a couple of months.
Heck, I just read the docs of hack for 2 hours, and I already got a good sense of what the language can do. I worked with PHP internals, and a bunch of other languages in my career.
* as language we define the language, its syntax and semantics, not any other library or the ecosystem. And yes, the standard library is still just a library. Knowing a list of functions and parameters does not mean knowing a language.