I am struggling to remember actual Silverlight applications, the Playboy Archive, and I think the Library of Congress at some point offered part of its collection as a Silverlight application.
It was also a backdoorsy kind of way to limit cool new web applications to Windows. The Mac version was a feature laggard, when it did finally exist, and I don’t know if a Linux version was ever developed, but I’m pretty sure the answer was no for several years. Of course back then Mac and Linux support was considered irrelevant, and the idea of making a native app into a web app to support them wasn’t really taken seriously for a while either. Silverlight would have seen to that cross-platform future never coming to pass had Ballmer had his way, but well, a combination of market forces from iPhones, to HTML5, to Mozilla and eventually Google Chrome really kind of made something like Silverlight and eventually Adobe Flash moot. Flash at least had legacy applications and video streaming that kept it around, Silverlight had to bet on its own future and to a web surfer it just wasn’t different enough from Flash nor did it ever have the install-base of Flash.