The big draw for me is to be able to actually invent and innovate and not just implement old ideas over and over in a boring corporate space. All the exciting research jobs I see in my field (NLP) require a PhD, so I feel like I'll hit a career ceiling at some point and be implementing boring corporate solutions for the rest of my life and never really innovating.
But as you say, appearances can be deceptive and it's like the grass is always greener, so maybe I need to broaden my horizons somehow. It's definitely hard to find that path at the moment though.
Edit: Oh and I do have to admit the fancy title that lets me feel like I'm truly educated and learned, and satisfies credentialism in the world is a draw too... Peer pressure is a hell of a drug