As a nation, we spend more one education than the military ($972B as of 2007 according to wikipedia, vs about $725B for the military including wars). A 1% increase in efficiency would save a little less than $10 billion, and a 16% increase in efficiency (using 2007 numbers) would be sufficient to balance the federal budget deficit [1].
If the Khan Academy is not striving to reduce our need for human teachers, we should create an organization that will.
[1] Edit: I should note that education is paid for primarily by the state and local governments, so it wouldn't be directly possible to reduce the federal budget by such savings. I was solely trying to make an order of magnitude comparison.