For the record, I think it's irrelevant.. but absolutely I think it's true. It doesn't mean .NET isn't capable, or that lots of .NET programmers aren't capable...
Just that .NET is way more popular in the enterprise than on the web, and that the work that gets done at most of those enterprise shops wouldn't fly on large sites.
It may be popular to pretend that the .NET camp (and to a slightly lesser extent, the Java Enterprise one) doesn't bend this way statistically, but they do.