Doesn't that depend on how you measure it, like accidents per miles or accidents per hours? Even if it would be safest by miles, I don't think it would follow that the safest way to get to work every morning would be by plane. It only works because airplanes go long distances, and accidents most frequently happen during starting or landing. In short, the comparison is not even very useful.
The question is also do we have to fly so much/do we need so much energy. If there were no airplanes, would people just travel the same distances by car? I doubt it.