And I'm not entirely sure how you turn water (H₂O) into Methane (CH₄). Granted I barely passed freshman chemistry 33 years ago so my chemistry knowledge isn't so good, but as near as I can recall, there is no process that will turn that input into that output.
And again, even if the moon is a source of water, there's not a significant need for any water mining operation at the poles to have a colony around it or even any human staffing. Putting people there on even a semi-permanent basis would likely eliminate any gains to be had from using the moon as a source of water.
Even the space tourism doesn't call for settling the moon. No one lives on top of Mount Everest either.