It is legitimate to wonder why there is Tree when TreeView already exists. Let's do a little genealogy to get some context before answering.
Well, Tkinter is the standard Python interface to the Tk GUI toolkit. In the face of the competition, Tk guys added a new set of widgets: the famous Tk themed widget (ttk).
It was not just an increment like 1 + 1 = 2 but rather a new direction slightly different from the old one without loss of compatibility of course. This document is great to go deeper in the topic: https://core.tcl-lang.org/tips/doc/trunk/tip/48.md