Short of a system that takes samples and feeds the probe, and can calibrate automatically, how do you measure pH in-system long term? Is there a special kind of probe that stays in calibration for longer?
Short of a system that takes samples and feeds the probe, and can calibrate automatically, how do you measure pH in-system long term? Is there a special kind of probe that stays in calibration for longer?
There might be a clever way around this, like with a tech other than glass electrode, or some type of automation system with motors that raise and lower the probe into calibration solutions.
Something interesting: pH electrode response is nearly linear, and you can make the transfer function using entirely 2 (or 3 to compensate for non-linearity) calibration points. (voltage, pH, temp) No arbitrary coefficient required, other than maybe temp compensation.
Edit: I wonder if your sampling idea could kill 2 birds with one stone, if implemented well: By sampling using a mechanical system, you could measure regularly, and calibrate. Auto calibration, and avoid the lifetime reduction from immersion. Eg some type of motor/pump system connected to the electrode.
An additional problem I've seen is that the temperature sensor for compensation is almost always supposed to be on the circuit rather than in the probe or external. Which is fine in some applications but useless for example for heated aquariums.
If you don't want to recalibrate the probe all the time you probably need to figure out a solution to have the probe in a compartment that gets flooded with clean water vs sample fluid.
Probably too expensive to be practical.
For temp compensation: I'm not sure the best approach. Temp dependence is loose, so you can get away with a reasonable temperature error for most applications. I went with on-circuit air temp sensor, with the ability in the drivers to feed in an offboard value. This is a reasonable approximation in many cases, but as you point out, for heated tanks, large ones, in-ground ones, or open bodies of water etc, you need to measure water temp directly.