VAT is kinda a sales tax in Europe. It means sellers must charge 20% on top of any sale, and give it to the government. Very small companies are exempt.
Uber was arguing that they were just a platform like EBay, and that every individual driver was a small enough business that they didn't have to pay the tax. Uber paid the tax, but only on Ubers fee, not the total journey amount.
This ruling is the government deciding that the tax was due on the entire journey.