I want to second EconTalk. Fantastic podcast. He is very much a free-market economist tho. Feel free to correct me if I'm wrong, but I think he is of Austrian school of economics?
Nonetheless, humanity shines through in his conversations. I'd say this podcast is more about human condition through economics. Cannot recommend it enough. Some of my favs
[Mindbody problem, freewill](https://www.econtalk.org/john-horgan-on-mind-body-problems/)
[Healthcare](https://www.econtalk.org/christy-ford-chapin-on-the-evolutio...)
[Transaction cost and a mental model for uber/airbnb](https://www.econtalk.org/michael-munger-on-sharing-transacti...)