One of Fleming's first thermionic diode valves, 1889
collection.sciencemuseumgroup.org.uk
collection.sciencemuseumgroup.org.uk
That device would have three conductors, which you can see in the photos. Two for the filament, one for the "plate." Later, a fourth conductor called the "cathode" was added to be heated by the filament (rather than pulling charge directly from the filament) to make the first diodes.
There's something funny about how modern active components are designed to reduce how much heat they consume, but the first active devices required an active heating element to function at all.
They operated just fine with just a bare (or coated) filament.
De Forest himself, however, apparently did not understand how his audion worked, at least at first, and felt it necessary for it to contain some gas. There's an excellent short biography that I will post a link to if I can find it...
Edit: This is not the article I had in mind, but it shows that initially, De Forest's audion did not have a connection to the grid, and also that De Forest was unaware that the triode arrangement could be used to amplify, and considered it only an improved diode; it was Amstrong who discovered its amplification. IIRC (from the other article I have in mind) De Forest was able to appropriate the fruits of this seminal discovery by use of his audion patents (Armstrong was later screwed over by Sarnoff and committed suicide.)
https://history-computer.com/the-audion-history-of-the-audio...
Their shared implementation details mean you can wire a triode as a diode but I don't think it's even a better diode.
I would not have guessed that the first ones happened in 1889; Anyone have a favorite link for tube history?