The concrete absorbed oxygen not CO2. I don't think there was a crop failure so much as too many people, not enough plants? Apparently they also miscalculated the amount of sunlight coming through the windows and so the amount of photosynthesis occurring, so maybe that is form of crop failure: does X grams of crop have fewer calories in of its been light deprived?
This is a fantastic read https://dartmouthalumnimagazine.com/articles/biosphere-2-wha...
[..] Microbes in our organically enriched soils had produced carbon dioxide at a greater rate than our young plants could produce oxygen via photosynthesis. We discovered that most of the missing oxygen was converted to CO2 and had been absorbed by the unsealed concrete in our habitat.[..]
Don't mean to waive you off or anything, just never heard this before and it doesn't seem to make sense at first listen.
From https://www.nytimes.com/1993/10/05/science/too-rich-a-soil-s...
Source: https://interestingengineering.com/why-concrete-doesnt-actua...
If you are interested in the details I can recommend J.P. Severinghaus et al., “Oxygen loss in Biosphere 2“.
That sounds like a lot of carbon. Like, a lot. I'd expect that it would have to absorb enough carbon that it could displace some amount of the volume that it would have appeared as in tree form.
Can you fit a third of a small forest into the concrete around that small forest? It seems unlikely.