Oops I missed that part. Argument retracted. Yeah this isn't a good enough deal given his situation. I'd ask for a lot more equity or walk.
Honestly, I'd be a happy developer at $85k and 2% overall. But that's a huge step up from their offer.
Other considerations aside, why take any risk when you already have a sure thing? Whether they offer 1% or even 10% doesn't make much of a difference.