You need the temporary containers plug-in to manage it for you.
https://addons.mozilla.org/en-US/firefox/addon/temporary-con...
https://addons.mozilla.org/en-US/firefox/addon/temporary-con...
Firefox built the core container technology, which drives their built in Facebook container (isolating Facebook from everything else). But isolating everything has a lot of weird edge cases, and I can't blame them for not supporting it out of the box.