of course people can hear and distinguish mathematically pure intervals especially if demonstrated in these ways.
you said,
> This brings some practical musical advantages, but even the average listener can hear the difference, the loss of purity of harmony
which I interpreted as meaning that average listeners are both hearing and actively aware of this difference in their day-to-day exposure to equal-tempered music.
I am very skeptical of this claim, but perhaps this is not what you intended to imply? I can understand why my question would lead to yours and geofft's answers.