Go to a praxair in the states and ask what the difference is: tested to 5x9's and loaded into a vacuum pulled bottle. ANY O2 at pressure is suitable to for human consumption at the surface because ANY impurities that are actually harmful would explode at 200 bar. Anything else (say from a PSA nitrox generator) would only be things like Argon.
Ad hoc O2 is better than no O2.