Fossil fuels are dead (and here's why)
antipope.org
antipope.org
Maybe some medium earth orbit at say 7000 km altitude could work? Outside the radiation belts, but avoiding shadow. Getting payloads to 7000 km requires a lot more delta vee (=fuel) than to 300 km. You probably wouldn't want to use reusable chemical rockets for that part, instead an expendable chemical third stage. Or ion propulsion (maybe even a tug going back and forth), but then the going is slow and you will spend time in the radiation belts.
For supplying users already in space most of those issues just go away.