> There is a known connection between sunlight exposure and serotonin release so it seems like a reasonable explanation to me.
Indeed, but I guess what I'm saying is that the feeling you experience isn't further evidence that it's serotonin.
Your connection between the feeling and it being serotonin is purely based on the studies that have been done. Those studies are the evidence. The qualitative feeling we get doesn't add to the body of evidence.
That is what the original author was arguing against. People arguing with her online saying "I feel a dopamine rush, therefore it's dopamine that I'm experiencing. You can't tell me it's some other neurotransmitter."