The 1DollarScan site says they cut the spines off the books to scan them, so unless that isn't accurate, they aren't reselling the books.
It would be a waste of the resources invested in the production of that physical book to not find some productive use for that copy.
A potential compromise, if simply giving out the same PDF is legal, is them offering a big option saying "Our records indicate we have this book on file! Do you want us to immediately send you a PDF copy when we receive your book [potentially discounted pricing or even a percentage of resell profits], or would you like to wait for a scan?" So yeah, now they have to do something with the hard copies, either resell or donate.
Edit: No need to speculate, they claim to shred and recycle everything after processing.