While it isn't necessarily clear what peak performance means, MKL or OpenBLAS, for instance, is only ~100% of serial peak on large DGEMM for a value of 100 = 90; ESSL is similar. I haven't measured GEMV (ultimately memory-bound), but I got ~75% of hand-optimized DGEMM performance on Haswell with pure C, and I'd expect similar on POWER if I measured. Those orders of magnitude are orders off, even for, say, reference BLAS. I don't know why I need Python, but the software clearly exists -- all those things and more (like vectorized libm). You can even compile assorted x86 intrinsics on POWER, though I don't know how well they perform relative to on equivalent x86, but I think you're typically better off with an optimizing compiler anyway.
I've packaged a lot of HPC/research software, which is almost all available for ppc64le; the only things missing are dmtcp, proot, and libxsmm (if libsmm isn't good enough).