"Blameless" to me means you acknowledge that the ultimate problem isn't that someone made a mistake that caused an outage. The problem is that you had a system in place where someone could make a single mistake and cause an outage.
If someone fat-fingers a SQL query and drops your database, the problem isn't that they need typing lessons! If you put a DBA in a position where they have to be typing SQL directly at a production DB to do their job, THAT is the cause of the outage, the actual DBA's error is almost irrelevant because it would have happened eventually to someone.