JWST is immensely complex.
Put another way, if launch costs were cheaper, it would also have been cheaper to design and build the telescope.
With its 8m diameter, Starship could house larger telescopes without folding. Considering how cheap a Starship by itself is, the Starship itself could be the permanent housing of a large telescope. It would just need to jettison the tip to expose the telescope inside.
From the Wiki "LUVOIR would be able to analyze the structure and composition of exoplanet atmospheres and surfaces. It could also detect biosignatures arising from life in the atmosphere of a distant exoplanet."
Proposed launch date 2039 (quite a wait).
[1] https://en.wikipedia.org/wiki/Large_Ultraviolet_Optical_Infr... [2] https://upload.wikimedia.org/wikipedia/commons/a/aa/Comparis...