1. Solar flares
2. Rogue AI
3. World war
3. Water scarcity (tied to war above)
5. Pandemic
6. Climate disasters
My naive perception heavily weighs future possible technological progress. Solar flare collapse is basically unmitigable due to a combination of unpredictability and deep systemic interdependence and dependence on susceptible technologies. Some governments paid lip service to this risk in the past, allegedly pushing to plan for this risk. Ultimately, only some organizations will have the resources to sustain the acute impact of a solar flare, but what good is Google if they're the only ones with working computers?
With climate, I'm very optimistic about the innovation that will result from economic and social pressures. I think 10 years ago I would have rated it at #2.
Edit: What are the chances. As I wrote this, JET started live-streaming an announcement about fusion energy...