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Others have already mentioned the location between Kyiv and the Belarusian border. Another reason could be that there are huge wetlands on the Ukraine–Belarus border, with only a few major roads across. If Russia wants to move troops and supplies in that general region, they have to pass by Chernobyl.

It's on the way to Kiev, the exclusion zone means there are no large urban settlements to fight over, and it's also using the West's weaknesses against itself - reality: topsoil has somewhat elevated levels of radiation compared to normal background radiation. The sarcophagus around the molten core is basically indestructible. public perception: radioactive cloud will make all Europe uninhabitable

- shortest path to Kyiv from Belarus - you can't really bomb them now at this location in order to push back