- Lead-free solders don't wet/flow as well as leaded, which causes lower manufacturing yields.
- Lead-free solders are generally more brittle and subject to earlier fatigue failures than leaded solders, so the lead-free units often fail prematurely (compared to leaded ones).
[1] https://nepp.nasa.gov/whisker/reference/tech_papers/2005-dad...
I’ve personally experienced tin whiskers growing between adjacent TQFP pins (resulting in product failures).
We successfully mitigated this with (1) electronic redesign so the whisker was likely to fuse (self-destruct melting via resistive heating) if it made contact with the adjacent pin in question, and (2) urethane conformal coating.
NASA studies such as https://nepp.nasa.gov/whisker/reference/tech_papers/2010-Pan... show that urethane conformal coating is effective against tin whiskers. But that does add another chemical and processing step and its own hazards.
The EU is doing the right thing though. Lead is bad for us and cumulative. And RoHS was about a lot more than just solder.
If you're worried about lead used in electronics and electrical systems, the focus should be lead-acid batteries, which use >10x more lead than circuit assemblies ever did. Lead-acid batteries were, however exempted from RoHS, while circuit assemblies were not.
Also at the time there was no alternative for these. Now that even UPSes are starting to use lithium, I think these will be banned sooner rather than later too.
But it's a tradeoff, because without the lead or the antimony, tin whiskers will eventually form. There is no known way to stop them, on a long enough timescale they will 100% certainly grow whiskers and eventually that will cause a failure.
Conformal coatings can reduce the rate of growth, but they don't stop it, and the conformal coating can itself cause failure as the tin whisker still grows and will exert mechanical pressure as it does.
RoHS = Restriction of Hazardous Substances, a directive that restricts the materials that can be used in electronic devices, forbidding manufacturers from using many known toxic materials. Initially adopted in the EU but then globally due to the necessity of exporting to the EU.
It would throw me off a bit at first but I got used to it quickly. Same as with driving on the other side when I moved over from Ireland :)
It's kinda hard to notice because it's so short and similar, I hadn't noticed myself until I read your comment.
ROHS is the acronym for a 2002 EU law called "Restriction of Hazardous Substances Directive"
https://en.wikipedia.org/wiki/Restriction_of_Hazardous_Subst...
Dealing with lead safely is much harder, and in a hobby setup can be assumed to be infeasible to be done correctly for nearly all people
- Spouse, Child or anyone sharing your apartment
- Technicians or similar which might enter your apartment
- Anyone living in your apartment after you
- Anyone to which you might sell the desk, used tool and similar
- In case of gross negligence you might also contaminate public transportation or e.g. a desk at a restaurant
- Police/Firefighters (in case they have to enter your apartment)
- ...
also many young people which start soldering as a hobby are not really aware about the health risk of solder, in which case lead free solder is still a better choice.
So no it's not just your problem.
And it doesn't matter if you specifically handle it correctly, most hobby soldering people do not and this is a general decision which is mainly about lead in hobby use cases (there are a bunch exceptions for companies).
Well and it's also about sold devices, because that also matter, children get there hand on them and there are various (sometimes surprising) ways how lead from soldering can get into the life of people using the product, instead of producing it.