I sold my motorcycle for coins.

I was buying a lot of article writing service (0% payment fees is nice!)

I shipped several orders from international customers in my http://store.gifti.us and accepted payments in bitcoins (0% foreign transaction fees is nice too!).

I bough steam codes.

I built somewhat profitable for short period of time site - http://betco.in and used some profit in bitcoins to pay for development work on open source project.

EDIT:

Bought, just like few other visitors, articles in PDF at http://ubitio.us. This is also project of mine and I am going to contribute it to open source soon, so just another bit into bitconomy.

And I am working on two other projects involving products/services and bitcoin :)

This is just what came in to my head right away...