Further, on the Amiga, any sensible pointers were generally 4-aligned anyway (you couldn't read words or longs from odd addresses and I think reading longs from 2-aligned addresses was slower, too, so nobody wanted to do that) so, theoretically, if you were to abuse this to the maximum effect you could've stashed 10 bits of excess payload data into an address: 8 bits in the bits 23-31 and 2 bits in 0-1 of an address. Any pointer was internally just a 32-bit address register value so you certainly had bits to spare!
I almost mentioned the fact that pointers were pretty much always aligned on the 68k, but I never really head of anyone using those bits to store anything. The top-8 had the "nice" property that the hardware did the masking for you.
I do remember that certain parts of the Amiga OS (particularly in the file system, I believe) used "BPTRs" which were essentially pointers shifted down 2 bits -- in other words, the word index instead of the individual byte index. Normal pointers were called "APTRs" by the code that used BPTRs.