I somehow missed the data-scraping introduction, that he sourced a fan-operated website that archives questions and answers. Here I'd thought he'd just off-handedly created a phenomenal data scraper for the general web.
He didn't talk much about the algorithm he used to present questions for optimal memorization. I imagine it was spaced repetition, as used in SuperMemo:
http://www.wired.com/medtech/health/magazine/16-05/ff_woznia...