PSON as you're describing it is basically PDF, with a couple of differences:
1. PDF has an "object table" so that you can refer to objects by number, permitting random access to the object graph, instead of requiring the whole file to be parsed from end to end.
2. PDF does permit comments, because not permitting comments would be a stupid idea.
3. PDF page contents are not represented as just a PSON object, but rather as a sequence of drawing operations.
By way of example, here's object 1750 from a random PDF file, which you can read in exactly the same way as your example above (so 37/T is two tokens: the integer 37 followed by the symbol T):
1750 0 obj
<</Linearized 1/L 791096/O 1752/E 12322/N 37/T 790286/H [ 483 540]>>
endobj
And here's some of the page contents from the same PDF, decompressed with Python zlib.decompress:
0.001 Tc -0.005 Tw -10.747 -1.02 Td
[(I)2(n)2(vest)1(men)2(t)1( )1(Co)2(n)2(f)1(eren)2(ce)]TJ
The TJ operator, as you can maybe guess, typesets a list of text strings interspersed with kerns, at the current point in the current font and so on.