If you want to try you need to imitate first the letter "R" as they do in France, which is roughly done by exhaling while keeping the upper rear part of the tongue in slight contact with the rear of the palate. It comes easy to me as I had this "R" pronunciation until about 17 when I started correcting it (with some of the family disapproving). Now do the same but not using any vocal cords, that is, only breath, then repeat also while inhaling. Keeping the mouth barely open helps a lot to give it its particular sound which with practice can become really close to a real cat purring.