Well, I was referring to the hypothesis that the release of previously sequestered methane caused the Permian-Triassic mass extinction event where 96% of marine species and 70% of land species died [1]. I think it's fair to say that a poisonous atmosphere is less habitable than no atmosphere.
[1] http://en.wikipedia.org/wiki/Permian%E2%80%93Triassic_extinc...