How would you describe behaviour?
But MSD is still can only describe a very basic behavior. Its only advantage over algorithms is that it’s more visual and adds a notion of a participant/actor.
If we’re talking about notation for describing behavior, then I prefer EventStorming for big picture, and Event Modeling for SW design. BPMN is also interesting, but much more technical and opionated. IMO it’s only useful if you’re already using a BPMN-based orchestration middleware.
Real-life workflows can be very complex, async, unordered, and non-deterministic. Just look at all manual bureaucratic processes that surround our daily life.
Or maybe you mean teaching the actual communication protocols like HTTP,FTP,SMTP,etc.?