Typical coal -> electricity is 33% efficient, but can be up to 50% [1], electricty to battery is 75% [2], and electric motors are about 92% [3]. The typical efficiency will be .33 * .75 * .92 = 23%, with a maximum of 35%. Gasoline engine efficiency is 25 - 30% [4], so we aren't really improving pollution much with electric cars, until wind/solar makes up a substantial part of our grid.
Now it will certainly _move_ the pollution from the cars in the cities to the power plants elsewhere (which is a good thing), but it really isn't preventing pollution.
[1] http://en.wikipedia.org/wiki/Fossil-fuel_power_station#Basic...
[2] http://www.futurepundit.com/archives/006554.html
[3] http://www.engineeringtoolbox.com/electrical-motor-efficienc...