The average car in the US emits 350 g CO2 per mile [1]. The average American commute is 40 miles [2]. That's 14 kg of CO2 per commuter, or 14 million kilograms per 1 million commuters. So, about 14000 tons of CO2 per day, or about 5 million tons per year. 5 MT.
Every year the US emits about 5 GT of CO2 equivalent [3]. If a million people stop commuting right now, the US will reduce its emissions by 0.1%.
[1] https://www.energy.gov/eere/vehicles/articles/fotw-1223-janu...
[2] https://www.zippia.com/advice/average-commute-time-statistic...
[3] https://www.epa.gov/ghgemissions/inventory-us-greenhouse-gas...