The average of one murder per murderer I'd generally agree with, but one of the Eton murderers killed 9 before committing suicide. So you are right to have qualms. But it is an upper bound and so still useful.
That said, one correction. El Salvador had a murder rate in 2017 of 61.7/100,000. This is comparable to Eton.
Let's take your analysis a step farther. If we have 230 * 30 people, each of whom has 1.1 chances in 100,000 of committing murder, the number of expected murderers is 0.0759. And the distribution of number of murders is a Poisson distribution. That means that the probability of k murders is λ^k e^(-λ) / k!.
Therefore our estimates are:
0 murderers = 0.9269088928142737
1 murderers = 0.07035238496460337
2 murderers = 0.0026698730094066973
3 murderers = 6.754778713798945e-05
Add those up and the expected probability of 4 or more murderers is only 1.3014245782150269e-06.
Therefore, even with a small absolute number, we can be very sure that the true murder rate for graduates of Eton are significantly higher than the UK population.
However Eton does attract people internationally. And the international murder rate in 2017 was 6.1/100,000 per https://worldpopulationreview.com/country-rankings/murder-ra.... Using that as a murderer rate, the odds against Eton producing 4 murderers in 30 years improve...to about 1/1000. Which means that Eton's murders are still likely to not be chance.