A gas is quite difficult to detect because it diffuses. This also makes them typically less dangerous because diffusion also means dilution. Levels do matter. Tritium is also pretty low in terms of radioactivity. The radiation cannot penetrate the skin except in very high levels (you can find keychains, watches, gun sights, etc with small bits of tritium and phosphorous to create long term glow objects). Ingestion and inhalation are more serious since your internal organs are more susceptible (see weighted dosage). The real cool thing is that we can measure radiation with high precision and in real time, so we can detect these dangers. Mostly because these devices are cheap.
In addition to the requirement of a more active approach needed to detect ground/water contaminants there are also a larger variety of pollutants that are harmful. Many of these need specific tests, which can consume your samples. Of course we can do pretty good guesstimates for what we should look for, but we do need to recognize that the process is both more fuzzy and more involved. We can grow these projects by making them cheaper, but that's a tall order (it is happening though).
Edit: I do want to note that most radiation detection devices do not distinguish between types of radiation. These differences do matter in danger levels. This can add complications the above but there is a decent signal that is still useful. But as with everything, some expertise and domain knowledge is quite important.