The western wildfires were absolutely mind-glowingly immense in ways we don't really deal with normally.
Five tank cars is 30,000 gallons * 5 = 150,000 gallons, roughly 600 cubic meters.
Safe exposure is 0.1 part per million, so 600 cubic meters * 10 million circle (assume the stuff never gets more than a meter off the ground, spherical cows and all that) = 45 kilometer radius circle. Obviously it's much more concentrated near the epicenter but let's assume it dispersed equally.
So 200 kilometers should be well outside the danger zone UNLESS a cloud of it doesn't disperse and instead heads in your direction.
If I had done a sphere (half a sphere to be precise) you'd get a half-dome only 1.5 km across.
I want to believe a burning river will get movement on this stuff but with the political climate I could see that being shrugged off since it's happened before so no big deal.
It's all quite insane. We are shortening our live expectancy as a nation in a measurable ways with proven solutions but instead we just shrug it off and do nothing.