No, it's more subtle than that. By wrapping in parenthesis, you're making it an expression. When you just say "{}+[]" in e.g. Chrome, the first {} is parsed as a block. So what you see printed is the result of "+[]", which is 0. This is why {}+[] is not equal to {}+[] without parens. This may also be why Node gives different results; I'm not sure.
I didn't mention any of this in the talk (it would've killed the flow ;). Instead, I glossed over it and interpreted the syntax as any sane programmer would.