Any possible work-around proved to be complicated and tedious--likely requiring heavy application-side logic--if not inadequate. Going hybrid was an option (RDBMS for critical parts, and NoSQL for other non-critical parts), but that may not have been a prudent way to start building this thing, since it would be difficult to predict the portions that might be correlated or codependent in the future (where a JOIN between the RDBMS and the NoSQL DB would be inefficient, if not impossible).
As a payments platform, we cannot afford to lose any transactions, and every penny must be accounted for, so a transactional and ACID-compliant data storage is a must. Thus, we decided to go with a traditional RDBMS. With that said, and looking towards the future, I am considering the use of an ultra-high throughput RDBMS such as VoltDB for our system... A VoltDB vs. MongoDB (or any other NoSQL DB) would be interesting.