I think the whole computing experience -- sitting upright in front of a screen with a mouse in your palm -- puts your mind in "hunting mode". Web surfing is all about clicking, clicking, clicking. It's like a videogame -- a series of clicks produces a reward (or not): a funny video, a witty exchange, an interesting piece of news, an update from a friend.
I think this induces a certain state of videogame-style excitement, which is incompatible with "calm consumption", as when you're reading a book. On the Web, one minute you're playing "the Web game", the next you're supposed to read a serious text on math, history or geography. But you can't focus because your brain wants to get another dopamine fix. You need to calm down first, which takes time.