Killjoy, I know, but you'd probably want to have permission from Spoon (or, more likely, Merge Records) before repurposing their most popular track commercially.

Similarly, annoying as it probably sounds, virtually anything a startup would ever want to do with a piece of music anyone has heard of before† is probably not kosher. On the flip side, there's thousands of amazingly talented musicians willing to record tracks for tiny amounts of money, so maybe investigate that instead of just grabbing random tracks from iTunes.

The obvious and (please presume) prolific apologies apply if rights to You Got Yr Cherry Bomb were secured for this. Totally possible.

† Including but not limited to putting it center stage on a cheerful and uplifting branded company blog post about resumes.