One basic problem with something like ACTA is that mostly it's "encouraging" countries to think and debate about "appropriate" measures and laws. A lot of the language is about "might" "should endeavor to" etc. – and it probably has to, or you might just clash with national legal concepts. So just signing it might imply a response from "Will do sir! Let's get the jackboots out!" to "Yeah, yeah, sure, we'll all have a nice chat about it…".
Still, signing it is a bad show of intent, a truly worrying symptom of current politics. It opens doors better left closed…