If you had a thin sheet of silicon filled with 0.2nm holes, wouldn't that be a membrane?
Also, if you take some fritted glass and wrap it around a solid core, such that the holes don't go anywhere — i.e. they're just pits that water molecules (but not anything larger) can enter, and then get stuck there by surface tension — then you've get https://en.wikipedia.org/wiki/Molecular_sieve s.
Some people have also experimented with single and double layers of graphene with a few very small pores. Because they are so thin, you don't need as much porosity for high transport rates.
You still have fouling issues, though.
That's literally individual silicon atoms removed
"The nearest neighbour distance is 0.235 nm" https://www.princeton.edu/~maelabs/mae324/glos324/silicon.ht...