I'm not. You can get a long way with conventional IPC, and OS processes provide a lot of value. For most PostgreSQL instances the TLB flush penalty is at least 3rd or 4th on the list of performance concerns, far below prevailing storage and network bottlenecks.
I share the concerns cited in this LWN story. Reworking this massive code base around multithreading carries a large amount of risk. PostgreSQL developers will have to level up substantially to pull it off.
A PostgreSQL endorsed "second-system" with the (likely impossible, but close enough that it wouldn't matter) goal of 100% client compatibility could be a better approach. Adopting a memory safe language would make this both tractable and attractive (to both developers and users.) The home truth is that any "new process model" effort would actually play out exactly this way, so why not be deliberate about it?